Vibration-Powered Catalyst Converts CO2 into CO at Five Times the Rate

A New Catalyst for CO2 Conversion

Researchers at the University of Osaka have developed a catalyst that uses mechanical vibration to convert carbon dioxide (CO2) into carbon monoxide (CO), an important chemical feedstock. The catalyst consists of barium titanate (BaTiO3) coated with a metal-organic framework (MOF)—a porous material that captures and concentrates CO2 near the catalyst surface—and incorporates isolated copper (Cu) atoms as reaction sites.

According to the research team, led by Assistant Professor Yoshifumi Kondo, the design concentrates CO2 near the Cu sites and helps direct the electrical charges generated by vibration to where the reaction occurs. Under ultrasonic vibration, the catalyst produced CO at approximately five times the rate of pristine BaTiO3. The study was published in ACS Catalysis.

Overcoming Limitations in Piezocatalysis

Piezocatalysis uses piezoelectric materials that convert mechanical energy, such as vibration, into electrical charges that can drive chemical reactions at room temperature. However, CO2 does not dissolve well in water, limiting the amount that can reach the catalyst surface. Conventional piezocatalysts may also have too few reaction sites and may not use the piezo-induced charges efficiently.

The team developed BaTiO3 nanocubes coated with ZIF-8, a hydrophobic MOF with a high capacity for adsorbing CO2. They then introduced isolated Cu atoms as reaction sites into the coating. The resulting core-shell catalyst, called Cu-ZIF-8/BT, concentrates CO2 near the Cu reaction sites and facilitates the transfer of piezo-induced electrons to these sites.

Significant Rate Increase

In water at room temperature and without sacrificial reagents, Cu-ZIF-8/BT produced CO at a rate of 114 μmol g-1 h-1 under ultrasonic vibration. Pristine BaTiO3 produced 24 μmol g-1 h-1 under the same conditions. This result indicates that the new catalyst increased the CO production rate by 4.8 times—approximately fivefold.

Coating BaTiO3 with ZIF-8 without Cu increased the rate to 56 μmol g-1 h-1. In contrast, simply mixing Cu-ZIF-8 and BaTiO3 produced only 16 μmol g-1 h-1. These results show that close contact between the components is crucial for the catalytic performance.

Stability and Selectivity

The catalyst maintained its activity over five consecutive reaction cycles, and CO was the only detected carbon-containing reduction product. The researchers suggest that this strategy could contribute to lower-energy CO2 recycling and may also be useful in photocatalytic and electrocatalytic systems.